🔬 SLO 001: Salts - Properties and Formation

Q 1.1Explain the nature of salt formation, highlighting the role of the parent acid and base.

1. Salts are ionic compounds formed by the electrostatic attraction between oppositely charged ions.

2. The base/metal supplies the cation (positively charged ion).

3. The acid supplies the anion (negatively charged ion/acid radical).

4. The combination forms a neutral compound.

Q 1.2What is the fundamental force that holds a salt molecule together, and why is the resulting compound neutral?

1. The ions are held together by a strong electrostatic force of attraction (ionic bond).

2. The positive charge supplied by the cation equals the negative charge supplied by the anion.

3. Since the net charges balance, the salt is electrically neutral.

Q 1.3How do the terms Cation and Anion relate to their parent compounds (acid and base) in the context of salt formation?

1. The cation (e.g., Na⁺) is derived from the base/metal and replaces the hydrogen ion of the acid.

2. The anion (e.g., Cl⁻) is the acid radical derived from the acid.

3. The salt forms by combining the metal part of the base and the non-metal part of the acid.

🧊 SLO 002 & 003: Physical Properties & Structure

Q 2.1Why do salts typically exhibit high melting points and exist as solids at STP?

1. Salts form a rigid crystal lattice structure at STP.

2. Ions are bound by very strong electrostatic forces (ionic bonds).

3. A large amount of energy is required to break these bonds, causing high melting points.

Q 2.2Describe the stable lattice structure of an ionic compound under normal conditions.

1. Ionic compounds exist as crystalline solids under normal conditions.

2. Their ions arrange in a regular 3D structure called a crystal lattice.

3. Each ion is surrounded by oppositely charged ions, maximizing attraction and providing rigidity.

Q 2.3Give two key physical properties of salts and explain the underlying reason for each.

1. High melting point: due to strong electrostatic attractions.

2. Brittle nature: when layers shift, like charges align and repel, causing the crystal to fracture.

3. Hardness: strong forces lock ions into fixed positions.

🔌 SLO 004: Electrical Conductivity

Q 4.1Compare the electrical state of a solid salt and its molten state, and relate this to their conductivity.

1. Solid salts: ions are fixed in the lattice and immobile, so they do not conduct electricity.

2. Molten salts: heating frees ions, making them mobile and able to conduct electricity.

3. Mobile ions carry charge, so molten salts are good conductors.

Q 4.2Explain the role of 'mobile ions' in the electrical conduction of an aqueous salt solution.

1. When a salt dissolves, it dissociates into ions.

2. Cations move to the cathode and anions move to the anode.

3. This coordinated movement of charged ions constitutes the electric current.

Q 4.3Solid NaCl does not conduct electricity, but NaCl dissolved in water does. Give three reasons for this difference.

1. In solid NaCl ions are fixed in the lattice.

2. In aqueous solution, polar water molecules pull ions out of the lattice.

3. Ions become mobile and can carry current.

💧 SLO 005: Solubility Rules

Q 5.1State three general solubility rules that determine if a salt will dissolve in water.

1. All salts of Sodium (Na), Potassium (K), and Ammonium (NH₄) are soluble.

2. All salts containing the Nitrate ion (NO₃) are soluble.

3. Most Chlorides are soluble except for Lead (Pb²⁺) and Silver (Ag⁺).

Q 5.2Do you think that most carbonates are soluble in water? State the rule and give two exceptions.

1. Most carbonates are insoluble in water.

2. Exceptions: carbonates of Na⁺ and K⁺ are soluble (e.g., Na₂CO₃).

3. CaCO₃ (limestone) is an example of an insoluble carbonate.

Q 5.3Describe the process of precipitation. How do solubility rules help predict the formation of a precipitate?

1. Precipitation occurs when two soluble salts react and an insoluble product forms.

2. Solubility rules predict which product is insoluble and will separate as precipitate.

3. The insoluble product appears as a solid that settles out of the solution.

🛠️ SLO 006: Preparation and Purification

Q 6.1Briefly outline the main steps used to obtain a pure, dry sample of a soluble salt from a reaction involving an insoluble solid.

1. Filtration: remove unreacted excess solid from the solution.

2. Evaporation: heat the solution to concentrate it (saturated solution).

3. Crystallization: cool slowly to form pure crystals.

4. Drying: wash and dry the crystals to obtain the final product.

Q 6.2Explain the purpose of adding an 'excess' amount of insoluble reactant in salt preparation, and what is the role of filtration in this context?

1. Adding excess ensures the limiting reactant is fully consumed.

2. It prevents contamination of the final product with unreacted acid.

3. Filtration removes the unreacted excess solid, giving a pure aqueous salt solution.

Q 6.3How is the preparation of a salt using a metal or insoluble carbonate different from using a soluble alkali (base)?

1. Using metal/carbonate: add excess solid and then filter — straightforward purification.

2. Using soluble alkali: perform titration to get a neutral solution — requires precise measurement.

3. The excess method is easier because the excess reagent is insoluble and can be filtered out.

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